Carole Rossi

Book & Editorials

• Metallized reactive materials, a road to clean and sustainable pyrotechnics, Propellants Explos. Pyrotech. 2023, 48 (5) https://doi.org/10.1002/prep.202380531
• Miniaturized Pyrotechnic Systems, meet the performance need while limiting the environmental impact, Micromachines 2022, 13(3) https://doi.org/10.3390/mi13030376
• Engineering of Al/CuO reactive multilayer thin films for tunable initiation and actuation, Propellants Explos. & Pyrotech (2018) https://doi.org/10.1002/prep.201800045
• Al-based energetic nanomaterials - design, manufacturing, properties and applications, ISTE Ltd, London and John Wiley & Sons, New York, June 2015
• Two decades of research on nano-energetic materials,Propellants Explos. Pyrotech. 2014; 39, 323 https://doi.org/10.1002/prep.201480151
• Nanoscale energetic materials, J. Phys. Chem. Sol. 2010, 71, 57 https://doi.org/10.1016/j.jpcs.2009.10.015

Scientific Journals

• T. Wu, V. Singh, B. Julien, MI Mendoza-Diaz, F. Mesnilgrente, S Charlot, C. Rossi; Design and fabrication of a fast-response and low-energy input micro igniter, Sensors and Actuators A: Physical, 2024 115573
• V. Singh, T. Wu, C.Tenailleau, T. Hungria, A.Esteve, C. Rossi, Investigating the Reaction Mechanism of Zirconium as a Fuel in Reactive Multilayer Films via Multimodal Analysis, Chemical Engineering Journal, 2024 https://doi.org/10.1016/j.cej.2024.153357
• V. Singh, T. Wu, L. Salvagnac, A. Estève, C. Rossi, Ignition and Combustion Characteristics of Al/TiB2-Based Nanothermites: Effect of Bifuel Distribution, ACS Appl. Nano Mater. 2024, 7, 4, 3977–3987 https://doi.org/10.1021/acsanm.3c05578
• T. Wu, E. Hagen, H. Wang, D.J. Kline, M.R. Zachariah, C. Rossi, Achieving superior ignition and combustion performance of Al/I2O5 biocidal nanoenergetic materials by CuO addition, Combustion and Flame 259, 2024, 113190 https://doi.org/10.1016/j.combustflame.2023.113190
• Combustion model for thermite materials integrating explicit and coupled treatment of condensed and gas phase kinetics, Proceedings of the Combustion Institute, Volume 39 (2022) https://doi.org/10.1016/j.proci.2022.08.117
• How positioning of a hard ceramic TiB2 layer in Al/CuO multilayers can regulate the overall energy release behavior, Fuel, Volume 349, 2023, 128599 https://doi.org/10.1016/j.fuel.2023.128599
• Comprehending the influence of the particle size and stoichiometry on Al/CuO thermite combustion in close bomb: a theoretical study, Propellants Explos. Pyrotech, 2023 https://doi.org/10.1002/prep.202200334
• Pioneering insights into the superior performance of titanium as a fuel in energetic materials, Chemical Engineering Journal, 453, 2, 2023, 139922 https://doi.org/10.1016/j.cej.2022.139922
• Initial Stage of Titanium Oxidation in Ti/CuO Thermites: a Molecular Dynamics Study Using ReaxFF Forcefields, Physical Chemistry Chemical Physics, 2023, 25, 16, 11268 – 11277 https://doi.org/10.1039/D3CP00032J
• First-principles investigation of CuO decomposition and its transformation into Cu2O, Phys. Rev. Materials 6, 9, 096001 https://doi.org/10.1103/PhysRevMaterials.6.096001
• Influence of process parameters on energetic properties of sputter-deposited Al/CuO reactive multilayers, Nanotechnology (2022) 33 465704 https://doi.org/10.1088/1361-6528/ac85c5
• Atomic scale insights into the first reaction stages prior to Al/CuO nanothermite ignition: influence of porosity, ACS applied materials & interfaces 14 (25), 29451-29461 https://doi.org/10.1021/acsami.2c07069
• Selecting machine learning models to support the design of Al/CuO nanothermites, J. Phys. Chem. A (2022) 126, 7, 1245–1254 https://doi.org/10.1021/acs.jpca.1c09520
• Engineered porosity-induced burn rate enhancement in dense Al/CuO nanothermites, ACS Applied Energy Materials 2022, 5, 3, 3189–3198 https://doi.org/10.1021/acsaem.1c03805
• Effect of substrate–induced localized stress on the combustion properties of Al/CuO reactive multilayer films, Thin Solid Films, 740 (2021). https://doi.org/10.1016/j.tsf.2021.139000
• H. Jabraoui, A. Esteve, M. Schoenitz, EL. Dreizin, C. Rossi, Atomic scale insights into the first reaction stages prior to Al/CuO nanothermite ignition: influence of porosity, ACS Applied Materials & Interfaces 2022, 14 (25), 29451-29461https://doi.org/10.1021/acsami.2c07069
• S. Brotman, M. Djafari-Rouhani, S. Charlot, A. Estève, C. Rossi, A benchmark study of burning rate of thermites through a gasless model, Appl. Sci. 2021, 11(14), 6553 https://doi.org/10.3390/app11146553
• F. Sevely, X. Liu, T. Wu, F. Mesnilgrente, B. Franc, S. Assie-Souleille, X. Dollat, C. Rossi, Processing and Properties of Direct Written gas-generating Reactive Layers, ACS Appl. Polym. Mater. 2021, 3, 8, 3972–3980 https://doi.org/10.1021/acsapm.1c00513 https://hal.laas.fr/hal-03302390
• T. Wu, F. Sevely, S. Pelloquin, S. Assie-Souleille, A. Esteve, C. Rossi, Enhanced Reactivity of Copper Complex-Based Reactive Materials via Mechanical Milling. Combust. Flame 233 (2021) https://hal.archives-ouvertes.fr/hal-03312787/
• M. Mursalat, C. Huang, B. Julien, M. Schoenitz, A. Esteve, C. Rossi, E. L. Dreizin, Low-Temperature Exothermic Reactions in Al/CuO Nanothermites Producing Copper Nanodots and Accelerating Combustion, ACS Applied Nano Materials 2021 4 (4), 3811-382
• T. Wu, G. Lahiner, C. Tenailleau, B. Reig, T. Hungria, A. Estève, C. Rossi, Unexpected Enhanced Reactivity of Aluminized Nanothermites by Accelerated Aging, Chem Eng J 2021, 418, 129432 https://doi.org/10.1016/j.cej.2021.129432 
• B. Julien, H. Wang, E. Tichtchenko, S. Pelloquin, A. Esteve, M. R. Zachariah, C. Rossi, Elucidating the dominant mechanisms in burn rate increase of thermite nanolaminates incorporating nanoparticle inclusions, Nanotechnology 2021 32 (21) https://doi.org/10.1088/1361-6528/abe6c8
• E. Tichtchenko, A. Estève, C. Rossi, Modelling the self-propagation reaction in heterogeneous and dense media: application to Al/CuO thermite, Combust. Flame, 2021, 228, pp.173-183. https://doi.org/10.1016/j.combustflame.2021.01.040
• How thermal aging affects energetic properties of reactive Al/CuO nanolaminates: a joint theoretical/experimental study, Nanomaterials (2020)10, 2087 https://doi.org/10.3390/nano10102087
• Layered Al/CuO Thin Films for Tunable Ignition and Actuations. Nanomaterials 2020, 10 (2009) https://doi.org/10.3390/nano10102009
• Probing the reaction zone of nanolaminates at ~μs time and ~μm spatial resolution, ACS J. Phys. Chem. C (2020) https://doi.org/10.1021/acs.jpcc.0c01647 https://hal.inria.fr/hal-02873415/
• New coordination complexes-based gas-generating energetic composites, Combustion and Flame 219, 478-487 (2020) https://doi.org/10.1016/j.combustflame.2020.05.022
• A Beehive Inspired Hydrogen Photocatalytic Device Integrating a Carbo-benzene Triptych Material for Efficient Solar Photo-reduction of Seawater, Advanced Sustainable Systems (2020) 2000121 https://doi.org/10.1002/adsu.202000121
• Integration of Gold nanoparticles as a strategy to modulate the ignitability of nanothermite films, ACS Appl. Nano Mater. (2020) https://doi.org/10.1021/acsanm.9b02619 https://hal.inria.fr/hal-02885829/
• PyroMEMS as Future Technological Building Blocks for Advanced Microenergetic Systems, Micromachines 2021, 12(2), 118; https://doi.org/10.3390/mi12020118
• The role of alkylamine in the stabilization of CuO nanoparticles as a determinant of the Al/CuO redox reaction, Phys. Chem. Chem. Phys., 2019, Physical Chemistry Chemical Physics 21 (29) https://pubs.rsc.org/en/content/articlelanding/2019/CP/C9CP02220A
• Self-propagating combustion of sputter-deposited Al/CuO nanolaminates, Combustion and Flame 205, 389 (2019) https://doi.org/10.1016/j.combustflame.2019.04.031
• A redox reaction model for self-heating and aging prediction of Al/CuO multilayers, Combustion Theory and Modelling 1 (2019) https://doi.org/10.1080/13647830.2019.1584336
• A condensed phase model of the initial Al/CuO reaction stage to interpret experimental findings, J. Appl. Phys. 125, 035102 (2019), https://doi.org/10.1063/1.5063285
• Al Interaction with ZnO Surfaces, J. Phys. Chem. C 2018, 122, 31, 17856–17864 https://doi.org/10.1021/acs.jpcc.8b04952
• Correlation between DNA Self-Assembly Kinetics, Microstructure, and Thermal Properties of Tunable Highly Energetic Al-CuO Nanocomposites for Micro-Pyrotechnic Applications, ACS Appl. Nano Mat., 1 (9), 4716 (2018) https://doi.org/10.1021/acsanm.8b00939
• Effect of surface nano/micro-structuring on the early formation of microbial anodes with Geobacter sulfurreducens: Experimental and theoretical approaches, Bioelectrochemistry 121, 191 (2018) https://doi.org/10.1016/j.bioelechem.2018.02.005
• Structure and chemical characterization at the atomic level of reactions in Al/CuO multilayers, ACS Applied Energy Materials 1 (4), (2018) https://doi.org/10.1021/acsaem.8b00296
• Fast circuit breaker based on integration of Al/CuO nanothermites, Sensor & Actuator A 273, 249 (2018) https://doi.org/10.1016/j.sna.2018.02.044
• Controlled  growth and grafting of High-Density Au Nanoparticles on Zinc Oxide Thin Films by Photo-Deposition, Langmuir 34 (5), (2018) https://doi.org/10.1021/acs.langmuir.7b04105
• Investigation of Al/CuO multilayered thermite ignition, J. Appl. Phys. 121, 034503 (2017) https://doi.org/10.1063/1.4974288
• Role of Trimethylaluminum (TMA) in Low Temperature Atomic Layer Deposition of Silicon Nitride, ACS Chem. Mat. 29, 6022, 2017 https://doi.org/10.1021/acs.chemmater.7b01816
• Basic Mechanisms of Al Interaction with the ZnO Surface, ACS J. Phys. Chem. C,  121, 12788 (2017) https://doi.org/10.1021/acs.jpcc.7b02661
• A diffusion - reaction scheme for modelling ignition and self-propagating reactions in Al/CuO multilayered thin films, Journal of Applied Physics, 122, 155105 (2017) https://doi.org/10.1063/1.5000312
• Performance Enhancement via Incorporation of ZnO Nanolayers in Energetic Al/CuO Multilayers, ACS Langmuir 33 (41), pp 11086–11093, (2017) https://doi.org/10.1021/acs.langmuir.7b02964
• A multi-phase micro-kinetic model for simulating aluminum based thermite reactions, Combustion and Flame, 180 , 10–19 (2017) https://doi.org/10.1016/j.combustflame.2017.02.031
• Role of impurities, defects and their complexes on the trapping of hydrogen in bulk aluminum and on the Al(111) surface, Computational Materials Science 126 (2017) 272–279 https://doi.org/10.1016/j.commatsci.2016.09.047
• Effect of temperature and O2 pressure on the gaseous species produced during combustion of Aluminum, Chemical Physics Letters, 649 (2016) https://doi.org/10.1016/j.cplett.2016.02.048
• Self-organized Al2Cu nanocrystals at the interface of aluminum based reactive nanolaminates to lower reaction onset temperature, ACS App. Mat. & Inter. 8, 13104 (2016) https://doi.org/10.1021/acsami.6b02008
• Role of alumina coatings for selective and controlled bonding of DNA on technologically relevant oxide surfaces, J. Phys. Chem. C 119, 23527, 2 (2015) https://doi.org/10.1021/acs.jpcc.5b06820
• Enhancing the reactivity of Al/CuO nanolaminates by incorporing Cu at the interfaces, ACS App. Mat. & Inter. 22, 11713 (2015) https://doi.org/10.1021/acsami.5b02653
• Modelling the pressure generation in Alumino-based thermites, Propellants Explos. & Pyrotech 40, 402 (2015) https://doi.org/10.1002/prep.201400297
• NanoEnergetics as pressure generator for nontoxic impact primers: comparison of Al/Bi2O3, Al/CuO, Al/MoO3 nanothermites and Al/PTFE, Combustion & Flame 162, 1813 (2015) https://doi.org/10.1016/j.combustflame.2014.12.002
• Elementary surface chemistry during CuO/Al nanothermite synthesis: copper and oxygen deposition on Aluminum (111) surfaces, ACS Appl. Mater. Interfaces, 6, 15086 (2014) https://doi.org/10.1021/am503126k
• Interfacial chemistry in Al/CuO reactive nanomaterial and its role in exothermic reaction, ACS App. Mat. & Int. 5 (3), 605 (2013) https://doi.org/10.1021/am3019405
• High-Energy Al/CuO nanocomposites obtained by DNA Directed assembly, Advanced Functional Materials, 22, 323 (2012) https://doi.org/10.1002/adfm.201100763